|
|
copalyl_diphosphate <=> stemod-13(17)-ene + diphosphate
|
4.2.3.33
stemar-13-ene synthase
4.2.3.34
stemod-13(17)-ene synthase
|
–
–
|
| |
BRENDA:
BR48894;
BS444188
KEGG:
R09116
MetaCyc:
RXN-9291
|
|
|
|
ent-copalyl_diphosphate <=> ent-pimara-8(14),15-diene + diphosphate
|
4.2.3.30
ent-pimara-8(14),15-diene synthase
|
–
|
| |
BRENDA:
BR48890
KEGG:
R09121
MetaCyc:
RXN-7788
|
|
|
|
geranylgeranyl_diphosphate <=> ent-copalyl_diphosphate
|
5.5.1.12
copalyl diphosphate synthase
5.5.1.13
ent-copalyl diphosphate synthase
5.5.1.14
syn-copalyl-diphosphate synthase
|
–
–
–
|
| |
BRENDA:
BR40507;
BR44349;
BS386478
KEGG:
R02068;
R06298;
R06312
MetaCyc:
5.5.1.13-RXN;
RXN-4861;
RXN-8528
|
|
|
|
stemod-13(17)-ene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> syn-stemoden-19-oate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.111
9beta-pimara-7,15-diene oxidase
|
–
|
| |
MetaCyc:
RXN-15437
|
|
|
|
copalyl_diphosphate <=> 9beta-pimara-7,15-diene + diphosphate
|
4.2.3.35
syn-pimara-7,15-diene synthase
|
–
|
| |
BRENDA:
BR48895;
BS444409
KEGG:
R09117
MetaCyc:
RXN-4883
|
|
|
|
syn-stemoden-19-al + reduced_[NADPH-hemoprotein_reductase] + O2 <=> syn-stemoden-19-oate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15440
|
|
|
|
ent-copalyl_diphosphate <=> ent-sandaracopimara-8(14),15-diene + diphosphate
|
4.2.3.19
ent-kaurene synthase
4.2.3.29
ent-sandaracopimaradiene synthase
|
–
–
|
| |
BRENDA:
BR48889
KEGG:
R09120
MetaCyc:
RXN-4884
|
|
|
|
geranylgeranyl_diphosphate <=> ent-copalyl_diphosphate
|
5.5.1.12
copalyl diphosphate synthase
5.5.1.13
ent-copalyl diphosphate synthase
5.5.1.14
syn-copalyl-diphosphate synthase
|
–
–
–
|
| |
BRENDA:
BR40507;
BR44349;
BS386478
KEGG:
R02068;
R06298;
R06312
MetaCyc:
5.5.1.13-RXN;
RXN-4861;
RXN-8528
|
|
|
|
stemod-13(17)-ene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> syn-stemoden-19-ol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15438
|
|
|
|
syn-stemoden-19-ol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> syn-stemoden-19-al + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15439
|
|
|
|
copalyl_diphosphate <=> stemar-13-ene + diphosphate
|
4.2.3.33
stemar-13-ene synthase
|
–
|
| |
BRENDA:
BR48893
KEGG:
R09115
MetaCyc:
RXN-4882
|
|
|
|
ent-copalyl_diphosphate <=> ent-cassa-12,15-diene + diphosphate
|
4.2.3.28
ent-cassa-12,15-diene synthase
|
–
|
| |
BRENDA:
BR48888
KEGG:
R09119
MetaCyc:
RXN-4881
|
|
